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Structure Determination of Fatty Acids from Tunicamycin Complex
Authors:Akira Takatsuki  Kenji Kawamura  Yoshio Kodama  Teiichiro Ito  Gakuzo Tamura
Affiliation:1. Department of Agricultural Chemistry, The University of Tokyo, Bunkyo-ku, Tokyo, Japan;2. Pharmaceutical Development Laboratories, Meiji Seika Kaisha Ltd., Horikawa-cho, Saiwai-ku, Kawasaki;3. Central Research Laboratories, Meiji Seika Kaisha Ltd., Morooka, Kohoku-ku, Yokohama, Japan
Abstract:The structures of ten fatty acids, which were obtained by the hydrolysis of tunicamycin complex, were determined. GLC-mass, 1H NMR and IR spectra showed that the major acids were trans-α, β-unsaturated iso acids with the formula C14H28O2, C16H28O2, C16H30O2 and C17H32O2. The minor acids were α, β-unsaturated normal acids and saturated normal and iso acids.
Keywords:salicylic acid  azelaic acid  cellulase  systemic acquired resistance  Capsicum annuum L. var. grossum
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