Synthesis of (4aR, 10aS)-(—)-8-Methoxy-1,1,4a-trimethyl-2-oxo-1,2,3,4,4a,9,10,10a-octahydrophenanthrene,an Optically Active Intermediate for the Synthesis of Diterpenes |
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| Authors: | Takeshi Sugai Hideaki Tojo Kenji Mori |
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| Institution: | Department of Agricultural Chemistry, The University of Tokyo, Yayoi 1–1—1, Bunkyo-ku, Tokyo 113, Japan |
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| Abstract: | (4aR,10aS)-(—)-8-Methoxy-1,1,4a-trimethyl-2-oxo-1,2,3,4,4a,9,10,10a-octahydrophenanthrene, a useful intermediate for the synthesis of optically active diterpenes, was synthesized from (S)-3-hydroxy-2,2-dimethylcyclohexanone. |
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| Keywords: | Hypnum plumaeforme moss momilactone allelochemicals |
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