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Iguesterin,a new quinonoid triterpene from Catha cassinoides
Authors:Antonio G González  Cosme G Francisco  Raimundo Freire  Rosendo Hernández  José A Salazar  Ernesto Suárez
Institution:Department of Organic and Biochemistry, University of La Laguna, Instituto de Investigaciones Quimicas, C.S.I.C., Tenerife, Spain
Abstract:β-Amyrin, sitosterol, celastrol, pristimerin, tingenone and a new hydroxymethylene quinonoid dinor-triterpene iguesterine were isolated from the root bark of Catha cassinoides. The structure of iguesterine was determined spectroscopically and by synthesis from tingenone. Tentative assignments are given for the chemical shifts of the methyl groups of iguesterin, tingenone and some of their derivatives.
Keywords:Celastraceae  peralillo  sitosterol  β-amyrin  quinonoid triterpenes  iguesterin  celastrol  pristimerin  tingenone  PMR  
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