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Biosynthesis and metabolism of gramine in Lupinus hartwegii
Authors:Edward Leete
Abstract:The administration of l-tryptophan-[3-14C] to Lupinus hartwegii (3-day-old seedlings and 8-week-old plants) resulted in the formation of gramine-[methylene-14C], indicating that gramine is produced by the same biosynthetic route in this species as in barley. Radioactive indole-3-aldehyde, labelled specifically on its aldehyde carbon, was isolated from the 8-week-old plants. However no significant amount of this compound was detected in 7-day-old seedlings, and it is suggested that indole-3-aldehyde is formed by the metabolism of gramine in the maturing plant.
Keywords:Leguminosae  lupin  gramine  tryptophan  indole-3-aldehyde  alkaloid biosynthesis  alkaloid metabolism
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