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生物基聚酰胺研究进展
引用本文:黄正强,崔喆,张鹤鸣,付鹏,赵清香,刘民英. 生物基聚酰胺研究进展[J]. 生物工程学报, 2016, 32(6): 761-774
作者姓名:黄正强  崔喆  张鹤鸣  付鹏  赵清香  刘民英
作者单位:郑州大学材料科学与工程学院,河南 郑州 450001,郑州大学材料科学与工程学院,河南 郑州 450001,郑州大学材料科学与工程学院,河南 郑州 450001,郑州大学材料科学与工程学院,河南 郑州 450001,郑州大学材料科学与工程学院,河南 郑州 450001,郑州大学材料科学与工程学院,河南 郑州 450001
摘    要:生物基聚酰胺是指制备聚酰胺的原料来源于生物质材料,生物基聚酰胺的原料主要有生物基氨基酸、生物基内酰胺、生物基二元酸、生物基二元胺等。本文论述了不同生物基原料的来源、制备方法以及相应的生物基聚酰胺的性能;重点论述了生物基聚酰胺PA11和PA1010的原料制备方法、合成方法以及改性研究进展;对生物基聚酰胺的种类、产业化研究现状进行了总结,并对我国生物基聚酰胺的发展提出建议。

关 键 词:生物基,可再生原料,聚酰胺,制备工艺,性能
收稿时间:2016-01-09

Progress in bio-based polyamides
Zhengqiang Huang,Zhe Cui,Heming Zhang,Peng Fu,Qingxiang Zhao and Minying Liu. Progress in bio-based polyamides[J]. Chinese journal of biotechnology, 2016, 32(6): 761-774
Authors:Zhengqiang Huang  Zhe Cui  Heming Zhang  Peng Fu  Qingxiang Zhao  Minying Liu
Affiliation:School of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001, Henan, China,School of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001, Henan, China,School of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001, Henan, China,School of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001, Henan, China,School of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001, Henan, China and School of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001, Henan, China
Abstract:Bio-based polyamides are environment-friendly polymers. The precursors of bio-based polyamides come from bio-based materials such as castor oil, glucose and animal oil. Bio-based polyamides precursors include bio-based amino acids, bio-based lactams, bio-based diprotic acid and bio-based diamines. In this paper, we discussed the route of the precursors of bio-based polyamides that come from bio-based materials. We discussed the properties of bio-based polyamides. Bio-based PA11and bio-based PA1010 are well-known bio-based polyamides; we discussed the origin materials of the precursors, the route of manufacturing bio-based PA11 and PA1010, and their modifications status. The variety, classification and commercial production of bio-based polyamides were described in details, as well as bio-based polyamides development in China.
Keywords:bio-based   renewable resources   polyamides   synthesis route   properties
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