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Enantioselective epoxidation by an optically active hydroperoxide |
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| Authors: | Hans-Jü rgen Hamann,Eugen H ft,Marek Chmielewski,Sylvester Maciejewski |
| Affiliation: | Hans-Jürgen Hamann,Eugen Höft,Marek Chmielewski,Sylvester Maciejewski |
| Abstract: | Enantioselective epoxidation of prochiral allylic alcohols with optically active 4,6-di-O-acetyl-2,3-dideoxy-α-D -threo-hex-2-enopyranosyl hydroperoxide in the presence of Ti(O-i-Pr)4 gives chiral epoxy alcohols with moderate enantiomeric excess. © 1993 Wiley-Liss, Inc. |
| Keywords: | asymmetric induction capillary gas chromatography cyclodextrin stationary phases |