Molecular design, crystal structure, antimicrobial activity and reactivity of light-stable and water-soluble Ag-O bonding silver(I) complexes, dinuclear silver(I) N-acetylglycinate |
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Authors: | Noriko Chikaraishi Kasuga |
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Institution: | Department of Chemistry, Faculty of Science, Kanagawa University, Tsuchiya, Hiratsuka, Kanagawa 259-1293, Japan |
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Abstract: | The reaction in water of silver oxide with N-acetylglycine (H2acgly) possessing the partial structure, i.e. the OC-N-C-COOH moiety, afforded light-stable and water-soluble dinuclear silver(I) complex ∞{Ag(Hacgly)]2} (complex 1). X-ray crystallography revealed that complex 1 in the solid state formed a ladder polymeric structure based on bis(carboxylato-O,O′)-bridged centrosymmetric Ag2O4 core, which was different from the two previously reported structures of silver(I) glycinate. Complex 1 which only comprises labile Ag-O bonding showed a wide range of antimicrobial activities against selected bacteria, yeasts and molds. Complex 1 can also work as an useful silver(I) precursor for novel silver(I) cluster synthesis. |
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Keywords: | Light-stable and water-soluble silver(I) complexes Ag-O bonding N-acetylglycinate Ladder polymer Antimicrobial activities |
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