Excited state properties of lanthanide complexes: Beyond ff states |
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Authors: | Arnd Vogler Horst Kunkely |
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Institution: | Institut für Anorganische Chemie, Universität Regensburg, D-93040 Regensburg, Germany |
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Abstract: | Generally, metal-centered ff states dominate the discussion of the excited state properties of lanthanide complexes. In particular, the luminescence properties of Eu(III) and Tb(III) compounds have been studied in great detail for many decades. However, other types of excited states such as MC fd, MLCT, LMCT, MMCT and IL are also of interest. In this context, we have recently examined the excited state behavior of selected Ce(III), Ce(IV), Eu(II) and Gd(III) complexes which are luminescent and/or photoreactive. |
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Keywords: | Electronic spectra Luminescence Photochemistry Lanthanides Cerium Europium Gadolinium |
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