Pressure-tuning infrared and Raman spectra of trans-dichloro-bis[(diperfluoroethyl)phenylphosphine]platinum(II), trans-Pt[PPh(CF3CF2)2]2Cl2 |
| |
Authors: | Zhenhua Xu Pramesh N Kapoor |
| |
Institution: | a State Key Laboratory of Rare Earth Material Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China b Department of Chemistry, University of Delhi, Delhi 110 007, India c Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Que., Canada H3A 2K6 |
| |
Abstract: | Infrared and Raman spectra of solid trans-dichloro-bisdiperfluoroethyl(phenyl)phosphine]platinum(II), trans-PtPPh(CF3CF2)2]2Cl2, have been studied at high external pressures up to ∼50 kbar with the aid of a diamond-anvil cell. A gradual, pressure-induced phase transition, most probably second order, was observed in the 21-34 kbar pressure range. In the IR spectra, the bands assigned to the CF stretching modes of the CF3 groups exhibit larger pressure sensitivities than do those associated with the CF stretching modes of the CF2 groups, most probably because of their physical location on the outside in the molecules in the unit cell. The fairly high pressure sensitivities of the symmetric PtCl stretching mode in both the low and high pressure phases (0.46 and 37 cm−1/kbar, respectively) are considered to reflect the low force constant associated with the long PtCl bond length thus making this vibration more susceptible to compression. |
| |
Keywords: | Infrared Raman High pressure Phase transition Platinum Perfluoroalkylphosphine |
本文献已被 ScienceDirect 等数据库收录! |
|