Solvent influence on rate and mechanism of oxidation of ethylenediaminetetraacetatocobaltate(II) by periodate |
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Authors: | Ahmed A. Abdel-Khalek Mahmoud M. Elsemongy |
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Affiliation: | Chemistry Department, Faculty of Science, Kuwait University, P.O. Box 5969, Kuwait |
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Abstract: | The kinetics of the oxidation of CoII(EDTA)2− by IO4− were studied in various ethanol + water mixtures covering the range 7.9 to 58.0 wt% ethanol, at five different temperatures in the range 15–35 °C. The effect of solvent on the rate and mechanism of the reaction was investigated. An inner-sphere mechanism for the reaction was proposed and supported by the calculated activation parameters. |
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Keywords: | Author to whom correspondence should be addressed. |
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