Geometrical Configuration of 12,13-Epoxyoctadeca-9,11-dienoic Acid,a Product of the Reaction Catalyzed by Flaxseed Allene Oxide Synthase (CYP74A)期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Geometrical Configuration of 12,13-Epoxyoctadeca-9,11-dienoic Acid,a Product of the Reaction Catalyzed by Flaxseed Allene Oxide Synthase (CYP74A)

Authors:	N.?V.?Medvedeva,Sh.?K.?Latypov,A.?A.?Balandina,L.?Sh.?Mukhtarova,A.?N.?Grechkin author-information" > author-information__contact u-icon-before" > mailto:grechkin@mail.knc.ru" title=" grechkin@mail.knc.ru" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author

Affiliation:	(1) Kazan Institute of Biochemistry and Biophysics, Kazan Scientific Center, Russian Academy of Sciences, P. O. Box 30, Kazan, Tatarstan, 420111, Russia;(2) Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

Abstract:	The geometrical configuration of a short-living allene oxide reaction product that arises under the catalysis by flaxseed allene oxide synthase (CYP74A) was studied by NMR spectroscopy. The structure of (9Z, 11E)-12,13-epoxyoctadeca-9,11-dienoic acid was established for it from the results of the nuclear Overhauser effect measurements.

Keywords:	allene oxide configuration allene oxide synthase flax (Linum usitatissimum)
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