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First Evidences of the Formation of a Vanadyl(IV) Complex of Bleomycin
Authors:Enrique J. Baran
Affiliation:Facultad de Ciencias Exactas, Universidad Nacional de La Plata, La Plata, Argentina
Abstract:Results of visible/ultraviolet and infrared spectroscopic measurements, as well as chemical evidence are presented which support the formation of a 2:1 bleomycin-VO2+ complex. The information obtained also allows some considerations concerning the probable coordination sphere of the vanadyl ion.
Keywords:Address requests for reprints to Dr. J.G.M. van der Linden   Department of Inorganic Chemistry   University of Nijmegan   Toernooiveld   6525 ED Nijmegan   The Netherlands.
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