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Preparation of afterglow and photochromic fibrous mats from polypropylene plastics to detect ultraviolet light
Authors:Mohamed E El-Hefnawy  Ali I Ismail  Mohammed I Orif  Soha T Al-Goul  Abraham Elmushyakhi  Manal Abou Taleb
Institution:1. Department of Chemistry, Rabigh College of Sciences and Arts, King Abdulaziz University, Jeddah, Saudi Arabia;2. Department of Chemistry, Rabigh College of Sciences and Arts, King Abdulaziz University, Jeddah, Saudi Arabia

Department of Chemistry, Faculty of Science, The Hashemite University, P.O. Box 150459, Zarqa, Jordan;3. Marine Chemistry Department, Faculty of Marine Sciences, King Abdulaziz University, Jeddah, Saudi Arabia;4. Department of Mechanical Engineering, College of Engineering, Northern Border University, Arar, Saudi Arabia;5. Department of Chemistry, College of Science and Humanities, Prince Sattam Bin Abdulaziz University, Al-kharj, Saudi Arabia

Department of Polymer Chemistry, National Center for Radiation Research and Technology (NCRRT), Egyptian Atomic Energy Authority, P.O. Box 7551, Nasr City, Egypt

Abstract:Polypropylene textiles have been used in the development of various industrial products, such as automotives, plastic furniture, and medical tools. However, polypropylene resists dyeing due to a deficiency of active staining spots. Here, we developed a new strategy towards new afterglow and photochromic fibres from recycled polypropylene plastics using plasma-supported coloration with rare-earth activated aluminate nanoparticles (REANPs). Plasma curing was used to generate active dyeing sites on the polypropylene surface. A thin film of REANPs (2–10 nm) was deposited onto the plasma-pretreated polypropylene surface. Various analytical techniques were applied to inspect the morphology of the REANP-finished polypropylene fibres. The polypropylene dyeing activity was much improved after being exposed to plasma. Both photoluminescence analysis and Commission internationale de l’éclairage (CIE) laboratory coordinates proved that the polypropylene fibres exhibited a white colour in daylight and green in ultraviolet light. The thin afterglow layer immobilized onto the polypropylene surface exhibited an emission band of 524 nm upon excitation at 365 nm. The sliding angles dropped from 12° to 9°, but the contacting angles increased from 139.4° to 145.0° when the REANP ratio was raised. These findings show that REANP-finished polypropylene had good colourfastness, antimicrobial activity, and ultraviolet light blocking. Both stiffness and permeability to air of REANP-finished polypropylene were explored to designate excellent comfort characteristics.
Keywords:afterglow  plasma curing  rare-earth activated aluminate nanoparticles  recycled polypropylene plastic  textile fibres
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