Synthesis and X-ray structures of rhenium(I) carbonyl aminoalkoxide and aminocarboxylate complexes |
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| Authors: | Wenwu Wang Yaw Kai Yan |
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| Institution: | a Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore
b Natural Sciences and Science Education, National Institute of Education, Nanyang Technological University, 1 Nanyang Walk, Singapore 637616, Singapore |
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| Abstract: | The complexes Re{MeN(CH2CH2O)(CH2CH2OH)-κ3N,O,O}(CO)3] (1), Re{N(CH2CH2O)(CH2CH2OH)2-κ3N,O,O}(CO)3] (2), Me3NH]2(OC)3Re{N(CH2CO2)2-κ3N,O,O}CH2CH2{N(CH2CO2)2-κ3N,O,O}Re(CO)3] (3), Me3NH]2Re2{μ2-2,6-(O2C)2(C5H3N)-κ3N,O,O}2(CO)6] (4) and Re2{μ2-2,6-(OCH2)(C5H3N)(CH2OH)-κ2N,O}2(CO)6] (5) were synthesized in high yields via the reactions of Re2(CO)10] and Me3NO with MeN(CH2CH2OH)2, N(CH2CH2OH)3, EDTA, pyridine-2,6-dicarboxylic acid and pyridine-2,6-dimethanol, respectively. Complexes 1-5 were characterized by IR and 1H NMR spectroscopy, elemental analysis and X-ray crystallography. |
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| Keywords: | Rhenium Carbonyl Aminoalkoxide Aminocarboxylate Amine-oxide Oxidative alkoxylation |
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