Structural studies on novel Ru(II)-Binap complexes |
| |
| Authors: | Tilmann J. Geldbach Silvia Rizzato |
| |
| Affiliation: | a Laboratory of Inorganic Chemistry, HCI ETH Hönggerberg, 8093 Zürich, Switzerland
b Department of Structural Chemistry (DCSSI), and Faculty of Pharmacy University of Milan, 20133 Milan, Italy |
| |
| Abstract: | The solid-state structures for two complexes, 7 and 8, are reported. Complex 7 was prepared by treating Ru(OAc)2(Binap) with two equivalents of HBArF in toluene solution, and represents only the second solid-state structure of a Binap complex, in which the Binap is a 6e donor to the Ru(II). The bonding is maintained in solution as shown via 13C NMR studies. The unusual cation 8, as an  salt, arises from prolonged reaction of Ru(OAc)2(Binap) with wet HBF4 (and, subsequently, added HSbF6) in 1,2-dichloroethane. |
| |
| Keywords: | X-ray crystal structures Ruthenium complexes Binap |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
