Novel (oxazolinyl)phenyl phosphinite pincer ligand: Development of the first non-symmetrical, PCN type chiral palladium and platinum complexes |
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| Authors: | Yukihiro Motoyama |
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| Institution: | School of Materials Science, Toyohashi University of Technology, Tempaku-cho, Toyohashi, Aichi 441-8580, Japan |
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| Abstract: | Chiral palladium and platinum complexes bearing non-symmetrical, PCN pincer ligand, 6-methoxy-3-(4′-isopropyl-2′-oxazolin-2′-yl)phenyl diphenylphosphinite i-Pr-Phemox-OPPh2], are first synthesized via oxidative addition of (i-Pr-Phemox-OPPh2)Br 6 to Pd2(dba)3 · (CHCl3) or Pt(dba)2 and subsequent treatment with silver salts. |
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| Keywords: | Pincer ligand Palladium Platinum |
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