Reversible dehydration process in a novel three-dimensional covalent network based on pyrimidine-4,6-dionato bridging ligand |
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Authors: | Garikoitz Beobide Antonio Luque Urko García-Couceiro Juan P García-Terán Pascual Román |
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Institution: | Departamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apartado 644, E-48080 Bilbao, Spain |
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Abstract: | The novel metal-organic polymer Zn(μ-pmdt)(H2O)]n (1) (pmdt = pyrimidine-4,6-dionate) exhibits an extended three-dimensional network with two crystallographically independent pmdt bridging ligands, one zinc(II) atom and a coordinated water molecule. The Zn(II) atoms are located at the centre of a distorted ZnN2OOw tetrahedral chromophore. One of the pmdt ligands acts as tetradentate bridge linking four metal centers, while the other pmdt ligand shows a bidentate coordination mode bridging two metal centers. The compound shows a reversible dehydration process, involving a coordinated water molecule, to lead an amorphous anhydrous phase. This transition has been characterized by thermogravimetric and variable-temperature X-ray powder diffraction techniques. |
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Keywords: | Pyrimidine bridge Three-dimensional complex Zinc complex Crystal structure Reversible dehydration |
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