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Synthesis and structures of new salen complexes with bulky groups |
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| Authors: | Leon Dyers Jr. Donald VanDerveer |
| Affiliation: | a Department of Chemistry, Clark Atlanta University, 223 James P. Brawley Dr. SW, Atlanta, GA 30314, USA b Free Radical Metabolic Section, Laboratory of Pharmacology and Chemistry, National Institute of Environmental Health Sciences, Research Triangle Park, NC 27709, USA c Department of Chemistry, Clemson University, Clemson, SC 29634, USA |
| Abstract: | A new series of Schiff base complexes [Fe(III), VO(II), Pd(II), Cu(II), and Ni(II)] has been developed. The ligand possesses bulky t-pentyl groups at the 3- and 5-positions. The iron (III) complex is obtained in monomeric form with a square-pyramidal configuration while the copper complex is with square-planar configuration. |
| Keywords: | Schiff base ligand Salen Nickel complex Copper complex Palladium complex Iron complex Crystal structure |
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