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Synthesis, characterization and crystal structure of manganese (IV) complex derived from salicylic acid |
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| Authors: | Ram A Lal Samhita Bhaumik Mahesh K Singh Sanjesh Choudhury Arvind Kumar |
| Institution: | a Department of Chemistry, North-Eastern Hill University, Shillong 793022, Meghalaya, India b Department of Chemistry, Tripura University, Suryamaninagar 799130, Tripura, India c Department of Chemistry, Rice University, 1600 Main Street, MS-60, Houston, TX 77005, USA |
| Abstract: | The binuclear manganese (IV) Mn2(Hsal)4(OH)4] (H2sal = salicylic acid) complex has been obtained from a complex reaction mixture in methanol consisting of Mn(II)(OAc)2 · 4H2O, GS ( a reagent obtained by refluxing glycine and salicylaldehyde in 1:1 molar ratio in methanol), monosodium salicylate and pyridine. The compound contains a distorted octahedral MnO6 coordination unit of potential importance to high oxidation state manganese bimolecules. |
| Keywords: | Maganese (IV) complex Salicylic acid Crystal structure Spectroscopic data |
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