In situ ligands syntheses involving malic acid in hydrothermal condition |
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Authors: | Jing Lu Xiao-Yang Yu Qing-Feng Yang |
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Affiliation: | College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Department of Chemistry, Jilin University, Changchun, Jilin 130023, China |
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Abstract: | Three kinds of in situ ligands syntheses involving malic acid, i.e. hydration, intra-molecular dehydration and isomeric transformation, have been found during studying on the syntheses of compounds 1-5. According these results, it can be concluded that the nature of metal atom affects strongly the in situ ligand synthesis, vice versa; the in situ ligand synthesis is favorable to the formation of coordination compound. |
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Keywords: | In situ ligand synthesis Malic acid Metal nature Hydrothermal condition |
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