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Two triacylated and tetraglucosylated anthocyanins from Ipomoea asarifolia flowers
Authors:Pale Eloi  Kouda-Bonafos Marie  Nacro Mouhoussine  Vanhaelen Maurice  Vanhaelen-Fastré Renée
Affiliation:Laboratoire de Chimie Organique Appliquée, Département de Chimie, Unité de Formation et de Recherche en Sciences Exactes et Appliquées, Université de Ouagadougou 03 B.P. 7021, Ouagadougou, Burkina Faso. eloi_pale@univ-ouaga.bf
Abstract:Two triacylated and tetraglucosylated anthocyanins derived from cyanidin were isolated from the flowers of Ipomoea asarifolia and their structures elucidated using chemical, GC, MS and NMR methods (1H and 13C, TOCSY-1D, DQF-COSY, DIFFNOE and HMBC). These complex pigments were found to consist of cyanidin 3-O-[2-O-(6-O-E-caffeoyl-beta-D-glucopyranosyl)]-[6-O-[4-O-(6-O-E-3,5-dihydroxycinnamoyl-beta-D-glucopyranosyl)-E-caffeoyl]-beta-D-glucopyranosyl]-5-O-beta-D-glucopyranoside and cyanidin 3-O-[2-O-(6-O-E-p-coumaroyl-beta-D-glucopyranosyl)]-[6-O-[4-O-(6-O-E-p-coumaroyl-beta-D-glucopyranosyl)-E-caffeoyl]-beta-D-glucopyranosyl]-5-O-beta-D-glucopyranoside.
Keywords:Ipomoea asarifolia   Convolvulaceae   Acylated anthocyanins   Cyanidin   p-Coumaric acid   Caffeic acid   3,5-Dihydroxycinnamic acid
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