Asymmetric Diels-Alder reaction involving chiral benzimidazoles as organocatalysts |
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| Authors: | Mirgane Nitin A Karnik Anil V |
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| Institution: | Department of Chemistry, University of Mumbai, Vidyanagari, Kalina, Mumbai, India. |
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| Abstract: | (S)‐(−)‐2‐(α‐hydroxyethyl)‐benzimidazole and (S)‐(+)‐2‐(α‐hydroxybenzyl)‐benzimidazole work as chiral Brønsted bases (BBs) in Diels–Alder reaction between anthrone and maleimides under mild reaction condition. These chiral BBs cause asymmetric induction. Chirality, 2011. © 2011 Wiley‐Liss, Inc. |
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| Keywords: | chiral Brønsted bases enantioselective Diels–Alder reaction chiral HPLC |
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