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Efficient Perovskite Solar Cells Based on a Solution Processable Nickel(II) Phthalocyanine and Vanadium Oxide Integrated Hole Transport Layer
Authors:Ming Cheng  Yuanyuan Li  Majid Safdari  Cheng Chen  Peng Liu  Lars Kloo  Licheng Sun
Affiliation:1. Department of Chemistry, Organic Chemistry, KTH Royal Institute of Technology, Stockholm, Sweden;2. Wallenberg Wood Science Center, Department of Fibre and Polymer Technology, Chemical Science and Engineering, KTH Royal Institute of Technology, Stockholm, Sweden;3. Department of Chemistry, Applied Physical Chemistry, KTH Royal Institute of Technology, Stockholm, Sweden;4. State Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT–KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology (DUT), Dalian, China
Abstract:An organic–inorganic integrated hole transport layer (HTL) composed of the solution‐processable nickel phthalocyanine (NiPc) abbreviated NiPc‐(OBu)8 and vanadium(V) oxide (V2O5) is successfully incorporated into structured mesoporous perovskite solar cells (PSCs). The optimized PSCs show the highest stabilized power conversion efficiency of up to 16.8% and good stability under dark ambient conditions. These results highlight the potential application of organic–inorganic integrated HTLs in PSCs.
Keywords:dopant free  hole transport material  nickel(II) phthalocyanine  perovskite solar cells  vanadium(V) oxide
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