Enhanced Electrocatalysis for Energy‐Efficient Hydrogen Production over CoP Catalyst with Nonelectroactive Zn as a Promoter |
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| Authors: | Tingting Liu Danni Liu Fengli Qu Dengxing Wang Ling Zhang Ruixiang Ge Shuai Hao Yongjun Ma Gu Du Abdullah M Asiri Liang Chen Xuping Sun |
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| Institution: | 1. College of Chemistry, Sichuan University, Chengdu, Sichuan, China;2. College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shandong, China;3. Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang, China;4. Analytical and Test Center, Southwest University of Science and Technology, Mianyang, Sichuan, China;5. Chengdu Institute of Geology and Mineral Resources, Chengdu, Sichuan, China;6. Chemistry Department, King Abdulaziz University, Jeddah, Saudi Arabia |
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| Abstract: | As a non‐toxic species, Zn fulfills a multitude of biological roles, but its promoting effect on electrocatalysis has been rarely explored. Herein, the theoretic predications and experimental investigations that nonelectroactive Zn behaves as an effective promoter for CoP‐catalyzed hydrogen evolution reaction (HER) in both acidic and alkaline media is reported. Density function theory calculations reveal that Zn doing leads to more thermal‐neutral hydrogen adsorption free energy and thus enhanced HER activity for CoP catalyst. Electrochemical tests show that a Zn0.08Co0.92P nanowall array on titanium mesh (Zn0.08Co0.92P/TM) needs overpotentials of only 39 and 67 mV to drive a geometrical catalytic current of 10 mA cm‐2 in 0.5 m H2SO4 and 1.0 m KOH, respectively. This Zn0.08Co0.92P/TM is also superior in activity over CoP/TM for urea oxidation reaction (UOR), driving 115 mA cm‐2 at 0.6 V in 1.0 m KOH with 0.5 m urea. The high HER and UOR activity of this bifunctional electrode enables a Zn0.08Co0.92P/TM‐based two‐electrode electrolyzer for energy‐saving hydrogen production, offering 10 mA cm‐2 at a low voltage of 1.38 V with strong long‐term electrochemical stability. |
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| Keywords: | CoP density functional theory hydrogen evolution urea oxidation Zn promoter |
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