Narrowing the Gap between Theoretical and Practical Capacities in Li‐Ion Layered Oxide Cathode Materials |
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| Authors: | Maxwell D. Radin Sunny Hy Mahsa Sina Chengcheng Fang Haodong Liu Julija Vinckeviciute Minghao Zhang M. Stanley Whittingham Y. Shirley Meng Anton Van der Ven |
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| Affiliation: | 1. Materials Department, University of California Santa Barbara, Santa Barbara, CA, USA;2. Department of NanoEngineering, University of California San Diego, La Jolla, CA, USA;3. Chemistry and Materials Science and Engineering, State University of New York, Binghamton, NY, USA |
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| Abstract: | Although layered lithium oxides have become the cathode of choice for state‐of‐the‐art Li‐ion batteries, substantial gaps remain between the practical and theoretical energy densities. With the aim of supporting efforts to close this gap, this work reviews the fundamental operating mechanisms and challenges of Li intercalation in layered oxides, contrasts how these challenges play out differently for different materials (with emphasis on Ni–Co–Al (NCA) and Ni–Mn–Co (NMC) alloys), and summarizes the extensive corpus of modifications and extensions to the layered lithium oxides. Particular emphasis is given to the fundamental mechanisms behind the operation and degradation of layered intercalation electrode materials as well as novel modifications and extensions, including Na‐ion and cation‐disordered materials. |
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| Keywords: | energy storage layered oxides Li‐ion batteries phase transformations |
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