|
|||||
|
|
A concise synthesis of 5-amino-5-deoxyaldonic acids as monomers for the preparation of nylon 5 |
|
| Authors: | Falentin Céline Beaupère Daniel Demailly Gilles Stasik Imane |
| Institution: | Laboratoire des Glucides, UMR 6219, Université de Picardie Jules Verne, 33 Rue Saint-Leu F-80039 Amiens, France. |
| Abstract: | Saponification of 5-azido-5-deoxy-D-pentonolactones (ribo-, arabino-, xylo-) with NaOH gave the corresponding 5-azido-5-deoxyaldonic acids sodium salts which, after regeneration of the acid form followed by catalytic reduction, led to the target compounds in 98% overall yields. |
| Keywords: | d-ribono-1" target="_blank">5-Azido-5-deoxy-d-ribono-1 4-lactone- d-arabinono-1" target="_blank">5-Azido-5-deoxy-d-arabinono-1 4-lactone d-xylono-1" target="_blank">5-Azido-5-deoxy-d-xylono-1 4-lactone d-aldonic acids sodium salts" target="_blank">5-Azido-5-deoxy-d-aldonic acids sodium salts d-aldonic acids" target="_blank">5-Amino-5-deoxy-d-aldonic acids |
| 本文献已被 ScienceDirect PubMed 等数据库收录！ | |