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Manganese Tetraphenylporphyrins Catalyzed Selective Oxidation of Purine Derivatives |
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| Authors: | Raffaele Saladino Paola Carlucci Claudia Crestini Pietro Tagliatesta Donato Monti Tristano Boschi |
| Affiliation: | 1. Dipartimento A. B. A. C. , Università degli Studi della Tuscia , Via S. Camillo de Lellis, 01100, Viterbo, Italy;2. Dipartimento di Scienze e Tecnologie Chimiche , Università degli Studi di Roma “Tor Vergata” , Via della Ricerca Scientifica, 00133, Roma, Italy |
| Abstract: | Abstract The oxidation of purine derivatives using porphyrins as catalysts and dimethyldioxirane (DMDO) as oxygen atom donor is reported. The regioselectivity of the oxidation was found to be dependent on the presence of a free OH moiety on the N(9)-side chain of the substrate and on the structure of the catalyst. |
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