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The methoxatin semiquinone: a pulse radiolysis study
Authors:M Faraggi  R Chandrasekar  R B McWhirter  M H Klapper
Affiliation:1. Division of Organic Chemistry, Department of Chemistry, Engineering Faculty, Istanbul University-Cerrahpasa, 34320, Avcilar, Istanbul, Turkey;2. Department of Chemistry, Faculty of Science, Gebze Technical University, 41400, Gebze, Kocaeli, Turkey;3. Department of Chemical Engineering, Engineering Faculty, Marmara University, 34722, Goztepe, Istanbul, Turkey
Abstract:Methoxatin is a novel o-quinone found in bacterial dehydrogenases and mammalian plasma amine oxidase. This is the first report of the redox potential and spectrum of the 1-electron reduced methoxatin semiquinone obtained by the method of pulse radiolysis in aqueous solution.
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