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Chemical constituents from Stenosolenium saxatile (Pall.) Turcz. (Boraginaceae)
Institution:1. Baotou Medical College, No. 31 Construction Road, Baotou, Inner Mongolia 014060, China;2. Guangxi Botanical Garden of Medicinal Plants, Nanning 530023, China;3. Inner Mongolia Institute of Traditional Chinese Medicine, Hohhot, Inner Mongolia 010020, China;1. Division of Botany, Department of Biology, Faculty of Science, Hacettepe University, Ankara, Turkey;2. Division of Botany, Department of Biology, Faculty of Science, İstanbul University, İstanbul, Turkey;1. Department of Physics and Measurements, Institute of Chemical Technology Prague, Technicka 5, Prague 6 CZ-166 28, Czech Republic;2. Department of Analysis of Functional Materials, Institute of Physics AS CR v.v.i, Na Slovance 1999/2, Prague 8 CZ-182 21, Czech Republic;1. School of Physics and Optoelectronic Technology, DUT, Linggong Road, Dalian 116024, China;2. School of Energy and Power Engineering, DUT, Linggong Road, Dalian 116024, China;1. Nanotechnology Research Institute, Faculty of Chemical Engineering, Babol Noshirvani University of Technology, Babol, Iran;2. Department of Chemistry, Qaemshahr Branch, Islamic Azad University, Qaemshahr, Iran
Abstract:Chemical investigation on the whole plants of Stenosolenium saxatile led to the isolation of three naphthoquinones (13), five pyrrolizidine alkaloids (PAs) (4–8), and six phenolic acids (9–14). The structure of the isolated compounds was elucidated by different spectrometric methods (1H NMR, 13C NMR and ESI-MS). These results are the first chemical data on constituents of this genus. The chemotaxonomic relationships between the genera Stenosolenium, Onosma, Arnebia, Echium and Lithospermum are also discussed.
Keywords:Boraginaceae  Naphthoquinones  Pyrrolizidine alkaloids  Chemotaxonomy
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