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A new sapogenin in the saponins of Zizyphus jujuba,Hovenia dulcis and Bacopa monniera
Authors:Ken-Ichi Kawai  Toshiyuki Akiyama  Yukio Ogihara  Shoji Shibata
Institution:Faculty of Pharmaceutical Sciences, University of Tokyo, Bunkyo-ku, Tokyo, Japan
Abstract:Acid hydrolysis of the saponin of the seeds of Zizyphus jujuba afforded ebelin lactone, which yielded the sapogenin, jujubogenin, on Smith-de Mayo degradation. The mechanism of conversion of jujubogenin into ebelin lactone has been elucidated. Hovenoside G of Hovenia dulcis and bacoside A of Bacopa monniera which produce ebelin lactone on acid hydrolysis have also been found to yield jujubogenin on Smith-de Mayo degradation.
Keywords:Rhamnaceae  Scrophulariaceae  jujuboside A  jujuboside B  hovenoside G  bacoside A  ebelin lactone  
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