Iridium(III)-vinylidene chemistry: Conversion of an iridacyclopentadiene-chlorido complex and terminal alkynes to iridacyclopentadiene-vinyl complexes

The reactions of κ²(C¹,C⁴)-CRCRCRCR](PPh₃)₂Ir(Cl) (9, R = CO₂Me) with propargyl alcohol derivatives (2-propyn-1-ol, 2-methyl-3-butyn-2-ol, 1-ethynylcyclopentanol, and 1-ethynylcyclooctanol), in the presence of water leads to the formation of iridium(III)-vinyl complexes bearing the general structure κ²(C¹,C⁴)-CRCRCRCR](PPh₃)₂Ir(CO)(κ¹-vinyl) where vinyl = -CHCH₂, -(E)-CHCHMe, -CHC(CH₂)₄, or -CHC(CH₂)₇. In these, the CO ligand was derived from the terminal carbon of the starting alkyne and the oxygen atom from water. Under anhydrous conditions, 9 undergoes reaction with 2-propyn-1-ol to give trimethyl 1,3-dihydro-3-oxo-4,5,6-isobenzofurantricarboxylate, the result of a cycloaromatization/transesterification involving the buta-1,3-dien-1,4-diyl ligand in 9 and 2-propyn-1-ol.