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Coordination behaviour of ferrocenylthiosemicarbazone in a novel hetero trinuclear nickel(II) complex: Synthesis, spectral, electrochemistry and X-ray crystallography |
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| Authors: | R. Prabhakaran S.V. Renukadevi M. Zeller |
| Affiliation: | a Department of Chemistry, Bharathiar University, Coimbatore 641 046, India b Department of Chemistry, Michigan State University, East Lansing, MI 48824, USA c Department of Chemistry, National Institute of Technology, Tiruchirappalli 620 015, India d Department of Chemistry, Youngstown State University, Youngstown, OH 44555-3663, USA |
| Abstract: | The coordination behaviour of ferrocenylthiosemicarbazone was investigated in a trinuclear [Ni(Fctsc)2] complex. The structure of the complex has been studied by X-ray crystallography. The complex crystallizes in rhombohedral space group  with six molecules per unit cell has the dimensions of a = 28.8042(2) Å, b = 28.8042(2) Å and c = 19.5131(3) Å, α = 90°, β = 90°, γ = 120°. The electronic communication between the metal centers has been studied by cyclic voltammetry. |
| Keywords: | Ferrocenylthiosemicarbazone Trinuclear complex NMR Cyclic voltammetry X-ray |
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