Highly Stable Supercapacitors with Conducting Polymer Core‐Shell Electrodes for Energy Storage Applications |
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Authors: | Chuan Xia Wei Chen Xianbin Wang Mohamed N. Hedhili Nini Wei Husam N. Alshareef |
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Affiliation: | Materials Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, Saudi Arabia |
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Abstract: | Conducting polymers such as polyaniline (PAni) show a great potential as pseudocapacitor materials for electrochemical energy storage applications. Yet, the cycling instability of PAni resulting from structural alteration is a major hurdle to its commercial application. Here, the development of nanostructured PAni–RuO2 core–shell arrays as electrodes for highly stable pseudocapacitors with excellent energy storage performance is reported. A thin layer of RuO2 grown by atomic layer deposition (ALD) on PAni nanofibers plays a crucial role in stabilizing the PAni pseudocapacitors and improving their energy density. The pseudocapacitors, which are based on optimized PAni–RuO2 core–shell nanostructured electrodes, exhibit very high specific capacitance (710 F g?1 at 5 mV s?1) and power density (42.2 kW kg?1) at an energy density of 10 Wh kg?1. Furthermore, they exhibit remarkable capacitance retention of ≈88% after 10 000 cycles at very high current density of 20 A g?1, superior to that of pristine PAni‐based pseudocapacitors. This prominently enhanced electrochemical stability successfully demonstrates the buffering effect of ALD coating on PAni, which provides a new approach for the preparation of metal‐oxide/conducting polymer hybrid electrodes with excellent electrochemical performance. |
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Keywords: | core– shell structures cycling stability polyaniline nanofiber arrays ruthenium dioxide ultrahigh power density |
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