Significance of Average Domain Purity and Mixed Domains on the Photovoltaic Performance of High‐Efficiency Solution‐Processed Small‐Molecule BHJ Solar Cells |
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| Authors: | Subhrangsu Mukherjee Christopher M Proctor Guillermo C Bazan Thuc‐Quyen Nguyen Harald Ade |
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| Institution: | 1. Department of Physics, North Carolina State University, Raleigh, NC, USA;2. Center for Polymers and Organic Solids and Materials Department, University of California, Santa Barbara, CA, USA;3. Center for Polymers and Organic Solids and Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA, USA |
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| Abstract: | Whereas the role of molecularly mixed domains in organic photovoltaic devices for charge generation is extensively discussed in the literature, the impact on charge recombination and thus fill factor is largely unexplored. Here, a combination of soft X‐ray techniques enables the quantification of phases at multiple length scales to reveal their role regarding charge recombination in a highly efficient solution processed small molecule system 7,7′‐(4,4‐bis(2‐ethylhexyl)‐4H‐silolo3,2‐b:4,5‐b′]dithiophene‐2,6‐diyl)bis(6‐fluoro‐4‐(5′‐hexyl‐2,2′‐bithiophen]‐5‐yl)benzoc]1,2,5]thiadiazole) (p‐DTS(FBTTh2)2) . A quantitative (linear) relationship between the average composition variations and the device fill‐factor is observed. The results establish the complex interrelationship between average phase purity, domain size, and structural order and highlight the requirement of achieving sufficient phase purities to diminish bimolecular and geminate recombination in solution processed small molecule solar cells. |
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| Keywords: | bulk‐heterojunctions morphology purities resonant soft X‐ray scattering small molecules solar cells |
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