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Synthesis of 2,3-unsaturated C-glycosides by HClO4-SiO2 catalyzed Ferrier rearrangement of glycals
Authors:Tiwari Pallavi  Agnihotri Geetanjali  Misra Anup Kumar
Institution:Division of Medicinal and Process Chemistry, Central Drug Research Institute (CDRI), Chattar Manzil Palace, Lucknow 226 001, India.
Abstract:Alkyl 2,3-unsaturated C-glycopyranosides have been prepared by Ferrier rearrangement of acyl or alkyl protected glycals catalyzed by HClO(4)-SiO(2).
Keywords:Ferrier reaction  Glycals  2  3-Dideoxy C-glycosides  HClO4-SiO2
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