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Characteristic new members of the phthiocerol and phenolphtiocerol families from Mycarbacterium ulcerans
Authors:Gurdyal S Besra  David E Minnikin  Amin Sharif  John L Stanford
Institution:Department of Chemistry, The University, Newcastle-upon-Tyne, U.K.;Department of Medical Microbiology, School of Pathology, University College and Middlesex School of Medicine, London, U.K.
Abstract:Abstract Dtacyl phtluodlolone A and phenolphthtodlo-lone A hpids were isolated from two stratus of Mycobactertum ulcerans . The dlol umts of the phthione A and phenolphth]odlolone A components were shown to have erythro stercochemistry by infrared spectroscopy and proton nuclear magnetic resonance of an acetal derivative This stereoehemistry is shared only by related dvols from M. marmum , the dhols from M. boys, M kansasu, M leprae and M. luberculosiss having threo stereochemlstry.
Keywords:Mycobacterum ulcerans            Lipids  Phthiocerol family  Phenolphthiocerol family
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