Mass spectrometry of the silver nitrate derivatives of cyclopropenoid compounds |
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| Authors: | T.A. Eisele L.M. Libbey N.E. Pawlowski J.E. Nixon R.O. Sinnhuber |
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| Affiliation: | Department of Food Science and Technology, Oregon State University, Corvallis, Oregon 97331, USA |
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| Abstract: | 1,2-dihexylcyclopropene, 1,2-diheptylcyclopropene, 1,2-dioctylcyclopropene, methyl malvalate, and methyl sterculate have been reacted with silver nitrate in methanol to form the corresponding methoxy and ketone derivatives. GLC, IR, and MS data are presented. The mass spectra and a possible method for determining the cyclopropene ring position are discussed. |
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