Laser-raman spectra of d-fructose in aqueous solution |
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Authors: | Mohamed Mathlouthi Dang Vinh Luu |
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Affiliation: | Institut Universitaire de Technologie, Département “Biologie Appliquée”, Université de Dijon, B.P. 510, 21014 Dijon Cédex France;Laboratoire de Spectroscopie Raman, Université des Sciences et Techniques du Languedoc, 34000 Montpellier France |
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Abstract: | Laser-Raman spectra of d-fructose in water at different concentrations were recorded, and assignments of the frequencies were proposed, based on earlier work on the Raman spectra of other sugars, and determination by other techniques of the composition of aqueous solutions of d-fructose as regards different isomers. It was found that the frequencies of vibration of the furanoid are higher than those of the pyranoid ring. The proportions of the furanoses and pyranoses, found from the ratio of the Raman intensities for the same modes of vibration, were similar to those found by other techniques. Shifts of intensities and frequencies were observed in the region of OH and CH bands, and were assigned to probable association between molecules of d-fructose and water. |
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