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The effect of microwave irradiation on Mo(VI) catalyzed transformations of reducing saccharides
Authors:Hricovíniová Zuzana
Institution:Institute of Chemistry, Slovak Academy of Sciences, SK-845 38 Bratislava, Slovakia. chemhric@savba.sk
Abstract:Efficient microwave-assisted Mo(VI)-catalyzed transformations of the 10 most common aldoses are described. Both pentoses and hexoses were converted to the corresponding epimers in considerably shorter reaction times. The yields were comparable, or better compared to conventional synthetic methods.
Keywords:Microwave  Isomerization  Saccharide  Mo(VI)-catalysis  Aldose/epialdose  Ketose/2-C-branched aldose
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