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Fourteen heliangolides from Calea species
Authors:Ferdinand Bohlmann  Ulrich Fritz  Robert M King  Harold Robinson
Institution:1. Institute for Organic Chemistry, Technical University of Berlin, D-1000 Berlin 12, W. Germany;2. Smithsonian Institution, Washington, DC 20560, U.S.A.
Abstract:The investigation of two further Calea species afforded, in addition to known compounds, fourteen new heliangolides, most of them being 11,13-epoxides. One lactone is a new type, a heliangolide substituted with a monoterpene residue. Furthermore, a new chromene and a new dithienyl derivative were isolated. The structures were elucidated by spectroscopic methods. The chemotaxonomic situation is discussed briefly.
Keywords:Compositae  sesquiterpene lactones  new heliangolides  myrtenyl heliangolide  new chromene derivative  new dithienyl derivative  
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