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Eudesmanolides and diterpenes from Wedelia trilobata and an ent-kaurenic acid derivative from Aspilia parvifolia
Authors:Ferdinand Bohlmann  Jürgen Ziesche  Robert M. King  Harold Robinson
Affiliation:1. Institute for Organic Chemistry, Technical University of Berlin, Strasse des 17. Juni 135, D-1000 Berlin 12, West Germany;2. Smithsonian Institution, Washington, DC 20560, U.S.A.
Abstract:The reinvestigation of the aerial parts of Wedelia trilobata afforded, in addition to known compounds, six new eudesmanolides, two ent-kaurenic acid derivatives as well as a degraded one. A corresponding hydroxy compound was present in Gnaphalium undulatum. From Aspilia parvifolia new ent-kaurenic acid epoxides were isolated. The structures were elucidated by spectroscopic methods. The chemotaxonomic situation is discussed briefly.
Keywords:Compositae  sesquiterpene lactones  eudesmanolides  degradated kaurene derivatives.
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