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Green synthesis of tellurium-doped SnO2 nanoparticles with sulfurized g-C3N4: Insights into methylene blue photodegradation and antibacterial capability
Authors:Misbah Umar  Humayun Ajaz  Mohsin Javed  Sana Mansoor  Shahid Iqbal  Sajid Mahmood  Abdul Rauf  Komal Aroosh  Ali Bahadur  Matar Alshalwi
Institution:1. Department of Chemistry, University of Engineering and Technology Lahore, Lahore, Pakistan

Contribution: Formal analysis, Resources, Writing - original draft;2. Department of Chemistry, University of Engineering and Technology Lahore, Lahore, Pakistan

Contribution: Conceptualization, ​Investigation, Project administration;3. Department of Chemistry, School of Science, University of Management and Technology, Lahore, Pakistan

Contribution: Data curation, ​Investigation, Methodology, Writing - review & editing;4. Department of Chemistry, School of Science, University of Management and Technology, Lahore, Pakistan

Contribution: Validation, Visualization, Writing - review & editing;5. Nottingham Ningbo China Beacons of Excellence Research and Innovation Institute, University of Nottingham Ningbo China, Ningbo, China;6. Nottingham Ningbo China Beacons of Excellence Research and Innovation Institute, University of Nottingham Ningbo China, Ningbo, China

Functional Materials Group, Gulf University for Science and Technology, Mishref, Kuwait

Contribution: Resources, Software, Visualization;7. Department of Chemistry, School of Science, University of Management and Technology, Lahore, Pakistan

Contribution: Methodology, Project administration;8. Department of Chemistry, School of Science, University of Management and Technology, Lahore, Pakistan

Contribution: ​Investigation, Software, Visualization;9. Department of Chemistry, College of Science, Mathematics, and Technology, Wenzhou-Kean University, Wenzhou, China;10. Department of Chemistry, Collage of Science, King Saud University, Riyadh, Saudi Arabia

Contribution: Funding acquisition, Supervision, Writing - review & editing

Abstract:The construction of SnO2 nanoparticles (NPs), specifically Te-doped SnO2 NPs, using a simple and economical co-precipitation technique has been thoroughly described in this work. NH3 served as the reducing agent in this procedure, whilst polyethylene glycol served as the capping agent. The primary goals of our work were to investigate the physicochemical properties of the synthesized SnO2 NPs and assess their potential use as antibacterial agents and photocatalysts. Scanning electron microscopy–energy dispersive X-ray, ultraviolet light, Fourier transform infrared spectroscopy, X-ray diffraction (XRD), and other analytical techniques were used to thoroughly analyze the NPs. Based on the full width at half maximum of the most noticeable peaks in the XRD spectrum, the Debye–Scherrer equation was used to calculate the crystallite sizes, which indicated the presence of a single tetragonal SnO2 phase. Particularly noteworthy was the exceptional photocatalytic activity of graphene-assisted Te-doped SnO2 NPs, achieving an impressive decomposition efficiency of up to 98% in the photo-oxidation of methylene blue. Furthermore, our investigation delved into the antibacterial attributes of the synthesized SnO2 NPs against Escherichia coli and Staphylococcus aureus, demonstrating inhibitory effects on both bacteria strains. This suggests potential applications for these NPs in various environmental and medical contexts.
Keywords:antibacterial agent  capping agent  co-precipitation  NPs  photocatalyst
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