Chiral calix[4]arenes bearing amino alcohol functionality as membrane carriers for transport of chiral amino acid methylesters and mandelic acid |
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Authors: | Bozkurt Selahattin Yilmaz Mustafa Sirit Abdulkadir |
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Institution: | Department of Chemistry, Sel?uk University, 42099 Konya, Turkey |
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Abstract: | Novel chiral calix4]arene derivatives bearing amino alcohol moieties at the lower rim have been synthesized from the reaction of p-tert-butylcalix4]arene diester with various amino alcohols. The transport of amino acid esters (phenylglycine, phenylalanine, and tryptophan methyl esters hydrochloride) and mandelic acid were studied through chloroform bulk liquid membrane system using chiral calix4]arenes 15-20. All these receptors have been found to act as carriers for transport of aromatic amino acid methylesters and mandelic acid from the aqueous source phase to the aqueous receiving phase. The influence of calixarene and guest structures upon transport through liquid membrane is discussed. |
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Keywords: | chiral calix[4]arene bulk liquid membrane amino acid methyl esters mandelic acid transport rate |
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