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Anaerobic digestion of starch-polyvinyl alcohol biopolymer packaging: biodegradability and environmental impact assessment
Authors:Guo M  Trzcinski A P  Stuckey D C  Murphy R J
Institution:Department of Biology, Imperial College of Science and Technology and Medicine, London SW7 2AZ, UK. miao.guo06@imperial.ac.uk
Abstract:The digestibility of a starch-polyvinyl alcohol (PVOH) biopolymer insulated cardboard coolbox was investigated under a defined anaerobic digestion (AD) system with key parameters characterized. Laboratory results were combined with industrial operational data to develop a site-specific life cycle assessment (LCA) model. Inoculated with active bacterial trophic groups, the anaerobic biodegradability of three starch-PVOH biopolymers achieved 58-62%. The LCA modeling showed that the environmental burdens of the starch-PVOH biopolymer packaging under AD conditions on acidification, eutrophication, global warming and photochemical oxidation potential were dominated by atmospheric emissions released from substrate degradation and fuel combustion, whereas energy consumption and infrastructure requirements were the causes of abiotic depletion, ozone depletion and toxic impacts. Nevertheless, for this bio-packaging, AD of the starch-PVOH biopolymer combined with recycling of the cardboard emerged as the environmentally superior option and optimization of the energy utilization system could bring further environmental benefits to the AD process.
Keywords:AD  anaerobic digestion  BFMSW  biodegradable fraction of municipal solid waste  BMP  biochemical methane potential  CHP  combine heat and power system  COD  chemical oxygen demand  CV  coefficient of variation (%)  GC  gas chromatograph  GWP100  global warming potential for 100-year time horizon  ICP-OES  inductive coupled plasma-optical emission spectrometer  LCA  life cycle assessment  LCIA  life cycle impact assessment  MSBF  maize starch-based foam  NF  nitrogen to protein conversion factor  ODP  ozone depletion potential  POCP  photochemical oxidation potential  PSBF  potato starch-based foam  PVOH  polyvinyl alcohol  SD  standard deviation  TN  total nitrogen  TS  total solids  TSS  the total suspended solid  VFAs  volatile fatty acids  VS  volatile solids  VSS  volatile suspended solid  WBF  wheat-based foam
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