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Le fucosterol-24,28 epoxyde,intermediaire dans la biodegradation oxydative du fucosterol en cholesterol par le criquet Locusta migratoria (R. ET F.)
Authors:Jean-Pierre Allais  Michel Barbier
Institution:Institut de Chimie des Substances Naturelles, CNRS, 91190-Gif-sur-Yvette, France
Abstract:β-Sitosterol 1 is metabolised to cholesterol 5 by phytophagous insects. It has been previously shown that fucosterol-24,28 epoxide 3 is transformed into 5 in Locusta migratoria, desmosterol 4 being an intermediate. It is now established that locusts transform 3-3H] fucosterol propionate into the corresponding labelled epoxide 3, recovered as such or as an oxazoline derivative 11.
Keywords:ERA 227  Université Paris-sud  91405-Orsay  France
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