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Easily recyclable chiral polymeric Mn(III) salen complexes for oxidative kinetic resolution of racemic secondary alcohols |
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| Authors: | Kureshy Rukhsana I Ahmad Irshad Pathak Kavita Khan Noor-Ul H Abdi Sayed H R Prathap Jaya K Jasra Raksh V |
| Affiliation: | Silicates and Catalysis Discipline, Central Salt and Marine Chemicals Research Institute, Bhavnagar 364 002, Gujarat, India. rukhsana93@yahoo.co.in |
| Abstract: | Chiral polymeric Mn(III) salen complexes were used efficiently for oxidative kinetic resolution of racemic secondary alcohols at room temperature. High chiral purity (ee; >99%) was achieved for the oxidative kinetic resolution of racemic secondary alcohols with 0.6 mol % catalyst loading in 60 min. The catalyst was easily recycled for five successive catalytic experiments. |
| Keywords: | polymeric Mn(III) salen oxidative kinetic resolution racemic secondary alcohols recyclable |
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