Integrated photocatalytic-biological reactor for accelerated 2,4,6-trichlorophenol degradation and mineralization |
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Authors: | Yongming Zhang Xia Sun Lujun Chen Bruce E Rittmann |
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Institution: | (1) Department of Environmental Engineering, College of Life and Environmental Science, Shanghai Normal University, Shanghai, 200234, People’s Republic of China;(2) School of Environment, Tsinghua University, Beijing, 100084, People’s Republic of China;(3) Swette Center for Environmental Biotechnology, Biodesign Institute, Arizona State University, Tempe, AZ 85287-5701, USA |
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Abstract: | An integrated photocatalytic-biological reactor (IPBR) was used for accelerated degradation and mineralization of 2,4,6-trichlorophenol
(TCP) through simultaneous, intimate coupling of photocatalysis and biodegradation in one reactor. Intimate coupling was realized
by circulating the IPBR’s liquid contents between a TiO2 film on mat glass illuminated by UV light and honeycomb ceramics as biofilm carriers. Three protocols—photocatalysis alone
(P), biodegradation alone (B), and integrated photocatalysis and biodegradation (photobiodegradation, P&B)—were used for degradation
of different initial TCP concentrations. Intimately coupled P&B also was compared with sequential P and B. TCP removal by
intimately coupled P&B was faster than that by P and B alone or sequentially coupled P and B. Because photocatalysis relieved
TCP inhibition to biodegradation by decreasing its concentration, TCP biodegradation could become more important over the
full batch P&B experiments. When phenol, an easy biodegradable compounds, was added to TCP in order to promote TCP mineralization
by means of secondary utilization, P&B was superior to P and B in terms of mineralization of TCP, giving 95% removal of chemical
oxygen demand. Cl− was only partially released during P experiments (24%), and this corresponded to its poor mineralization in P experiments
(32%). Thus, intimately coupled P&B in the IPBR made it possible obtain the best features of each: rapid photocatalytic transformation
in parallel with mineralization of photocatalytic products. |
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