Intramolecular catalysis of biomimetic Michael additions to cyclopentenones |
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Authors: | Stephen R. Wilson Hsuen-Tsi Chen |
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Affiliation: | Department of Chemistry, Indiana University, Bloomington, Indiana 47405 USA |
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Abstract: | A study of the Michael additon of n-propyl mercaptan to a series of cyclopentenones shows that intramolecular hydrogen bonding enhances the rate. The possible significance of this observation is discussed. |
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