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Intramolecular catalysis of biomimetic Michael additions to cyclopentenones
Authors:Stephen R. Wilson  Hsuen-Tsi Chen
Affiliation:Department of Chemistry, Indiana University, Bloomington, Indiana 47405 USA
Abstract:A study of the Michael additon of n-propyl mercaptan to a series of cyclopentenones shows that intramolecular hydrogen bonding enhances the rate. The possible significance of this observation is discussed.
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