The reaction of allitol with hydrogen halides |
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| Authors: | JM Ballard BE Stacey |
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| Institution: | Department of Chemistry, Sir John Cass School of Science and Technology, City of London Polytechnic, Jewry Street, London EC3N 2EY Great Britain |
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| Abstract: | The reaction of allitol with fuming hydrochloric acid at 100° afforded 1,4-anhydro-5,6-dichloro-5,6-dideoxy-DL-talitol (14) and 1,4-anhydro-6-chloro-6-deoxy-DL-allitol (3). 1,4-Anhydro-6-bromo-6-deoxy-DL-allitol (4) and 1,4-anhydro-DL-allitol (6) were obtained from a similar reaction with excess of hydrogen bromide. |
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