Environmentally friendly microwave ionic liquids synthesis of hybrids from cellulose and AgX (X = Cl,Br) |
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Authors: | Yan-Yan Dong Jing He Shao-Long Sun Ming-Guo Ma Lian-Hua Fu Run-Cang Sun |
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Institution: | 1. Beijing Key Laboratory of Lignocellulosic Chemistry, College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, PR China;2. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, PR China |
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Abstract: | The purpose of this article was to explore an environmentally friendly strategy to synthesis of biomass-based hybrids. Herein, microwave-assisted ionic liquids method was applied to fabricate the hybrids from cellulose and AgX (X = Cl, Br) using cellulose and AgNO3. The ionic liquids act simultaneously as a solvent, a microwave absorber, and a reactant. Ionic liquids provided Cl− or Br− to the synthesis of AgCl or AgBr crystals; thus no additional reactant is needed. The products are characterized by X-ray powder diffraction (XRD), Fourier transform infrared spectrometry (FTIR), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and differential thermal analysis (DTA). The cellulose–Ag/AgCl hybrid and cellulose–Ag/AgBr hybrid were also obtained by using cellulose–AgCl and cellulose–AgBr hybrids as precursors. This environmentally friendly microwave-assisted ionic liquids method is beneficial to the hybrids with high dispersion. |
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Keywords: | Hybrids Microwave Ionic liquids Cellulose AgCl AgBr |
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